This could all go pear shaped trying to informally slip things through. I'd suggest that you ensure that a transfer of title to your ex takes place when the money arrives, if that is the intention. However, be sure of valuations. If the actual gain based on market value is greater than the £20k, HMRC may still invoke related party rules and seek to calculate CGT based on MV.
As has already been mentioned, there will be relief available for the time that it was your principal private residence + 18 months, but there is still likely to be a chargeable gain which, if > than your exemption of £11,100 will give rise to a CGT payment.
If you aren't clear, I suggest that you seek professional advice where you can provide full details and get proper advise.
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